Effect of correlations in the interaction along polymer chain on the globule structure


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Resumo

A special potential for interaction between polymer chain units, whose energy decreases with increasing distance s between the units as s–1, was introduced for the first time. According to Monte Carlo simulation, interactions of this type result in the formation of a globule with an equilibrium packing of domains in space. The radius of gyration of a chain segment in these globules varies with segment length according to the scaling law typical of crumpled globules.

Sobre autores

A. Astakhov

Moscow State University; Semenov Institute of Chemical Physics

Email: vvvas@polly.phys.msu.ru
Rússia, Moscow, 119991; ul. Kosygina 4, Moscow, 119991

V. Ivanov

Moscow State University

Email: vvvas@polly.phys.msu.ru
Rússia, Moscow, 119991

V. Vasilevskaya

Nesmeyanov Institute of Organoelement Compounds

Autor responsável pela correspondência
Email: vvvas@polly.phys.msu.ru
Rússia, ul. Vavilova 28, Moscow, 119991

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