Email this article Electrochemical synthesis of cobalt polyporphine films
- Authors: Istakova O.I.1,2, Konev D.V.1,2, Devillers C.H.3, Vorotyntsev M.A.1,2,3,4, Zyubin A.S.1, Antipov E.M.2,4, Aldoshin S.M.1,4
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Affiliations:
- Institute of Problems of Chemical Physics
- Mendeleev Chemical Technology University of Russia
- Institut de Chimie Moléculaire de I’Université de Bourgogne
- Moscow State University
- Issue: Vol 471, No 1 (2016)
- Pages: 181-184
- Section: Physical Chemistry
- URL: https://journals.rcsi.science/0012-5016/article/view/153570
- DOI: https://doi.org/10.1134/S0012501616110038
- ID: 153570
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Abstract
A method for modification of the inert electrode surface with an electroactive polymeric film containing the CoN4 catalytic site has been suggested and approved. The described approach affords the maximal content of the metal porphine moiety per unit weight of the coating. The classical method of introduction of an ion into the porphine macrocycle has been replaced by electrochemical polarization of an electrode with a metallated film in a dilute solution. The metalation efficiency has been demonstrated by the presence of changes in the current–voltage and spectral characteristics of the resulting polymeric films of the unsubstituted porphine pH2P and cobalt polyporphine pCoP.
About the authors
O. I. Istakova
Institute of Problems of Chemical Physics; Mendeleev Chemical Technology University of Russia
Email: dkfrvz@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Miusskaya pl. 9, Moscow, 125047
D. V. Konev
Institute of Problems of Chemical Physics; Mendeleev Chemical Technology University of Russia
Author for correspondence.
Email: dkfrvz@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Miusskaya pl. 9, Moscow, 125047
C. H. Devillers
Institut de Chimie Moléculaire de I’Université de Bourgogne
Email: dkfrvz@gmail.com
France, Dijon
M. A. Vorotyntsev
Institute of Problems of Chemical Physics; Mendeleev Chemical Technology University of Russia; Institut de Chimie Moléculaire de I’Université de Bourgogne; Moscow State University
Email: dkfrvz@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Miusskaya pl. 9, Moscow, 125047; Dijon; Moscow, 119991
A. S. Zyubin
Institute of Problems of Chemical Physics
Email: dkfrvz@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432
E. M. Antipov
Mendeleev Chemical Technology University of Russia; Moscow State University
Email: dkfrvz@gmail.com
Russian Federation, Miusskaya pl. 9, Moscow, 125047; Moscow, 119991
S. M. Aldoshin
Institute of Problems of Chemical Physics; Moscow State University
Email: dkfrvz@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
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