A New Approach to the Synthesis of Carboranylmethylsiloxanes
- 作者: Izmailov B.1, Vasnev V.1, Markova G.1
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隶属关系:
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- 期: 卷 486, 编号 1 (2019)
- 页面: 119-121
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154424
- DOI: https://doi.org/10.1134/S001250081905001X
- ID: 154424
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详细
An efficient method for the synthesis of o(m)-carboranylmethylsiloxanes by the Grignard reaction from 1,2(7)-bis(bromomagnesiummethyl)-o(m)-carboranes and 1-chloro-1,1,3,3,3-pentamethyldisiloxane has been developed. As a result, 1-(1,1,3,3,3-pentamethyldisiloxanylmethyl)-2(7)-methyl-o(m)-carboranes, 1,2(7)-bis(1,1,3.3,3-pentamethyldisiloxanylmethyl)-o(m)-carboranes, exocyclic 1,2-(o-carborano)-4,6-bis(dimethylsilyl)-5-oxacycloheptane, 1,7-bis(chloro-1,1,3,3-tetramethyldisiloxanylmethyl)-m-carborane, and oligomer containing two 1,7-bis(dimethylsilylmethyl)-m-carborane units have been obtained.
作者简介
B. Izmailov
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
俄罗斯联邦, Moscow, 119991
V. Vasnev
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
俄罗斯联邦, Moscow, 119991
G. Markova
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: mgaly@yandex.ru
俄罗斯联邦, Moscow, 119991