5,6-Bis(9-(2-decyltetradecyl)-6-fluoro-9H-carbazol-3-yl)naphtho[2,1-b:3,4-b']dithiophene as a Promising Donor Structure for D–A Conjugated Copolymers with a Narrow Bandgap
- 作者: Keshtov M.1, Kuklin S.1, Konstantinov I.1, Peregudov A.1, Xie Z.2, Ostapov I.3, Makhaeva E.3, Khokhlov A.1
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隶属关系:
- Nesmeyanov Institute of Organoelement Compounds
- State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry
- Moscow State University
- 期: 卷 482, 编号 2 (2018)
- 页面: 213-219
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154295
- DOI: https://doi.org/10.1134/S0012500818100014
- ID: 154295
如何引用文章
详细
A new carbazole-containing naphthodithiophene derivative—heteroaromatic compound 5,6- bis[9-(2-decyltetradecyl)-9H-carbazol-3-yl]naphtho[2,1-b:3,4-b']dithiophene (M1)—has been synthesized. The compound will be used by us as a weak donor structural block for fabricating narrow-bandgap D–A conjugated polymers. The composition and structure of M1 have been confirmed by elemental analysis data, IR spectroscopy, and 1H and 13C NMR. The synthesized compound has a low HOMO energy (–5.4 eV), which is favorable for a high open-circuit voltage. Monomer M1 can be used as a promising weak donor moiety in D–A conjugated polymers for solar photovoltaics.
作者简介
M. Keshtov
Nesmeyanov Institute of Organoelement Compounds
编辑信件的主要联系方式.
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
S. Kuklin
Nesmeyanov Institute of Organoelement Compounds
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
I. Konstantinov
Nesmeyanov Institute of Organoelement Compounds
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
A. Peregudov
Nesmeyanov Institute of Organoelement Compounds
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
Zhi-Yuan Xie
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry
Email: keshtov@ineos.ac.ru
中国, Changchun
I. Ostapov
Moscow State University
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
E. Makhaeva
Moscow State University
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991
A. Khokhlov
Nesmeyanov Institute of Organoelement Compounds
Email: keshtov@ineos.ac.ru
俄罗斯联邦, Moscow, 119991