New polyfunctional spiropyran of 1,3-benzoxazin-4-one series with carbonyl-containing substituents in the [2H]-chromene moiety
- 作者: Ozhogin I.1, Tkachev V.2, Lukyanov B.1,3, Shilov G.2, Mukhanov E.1, Vasilyuk G.4, Aldoshin S.2, Minkin V.1
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隶属关系:
- Research Institute of Physical and Organic Chemistry
- Institute of Problems in Chemical Physics
- Don State Technical University
- Yanka Kupala State University
- 期: 卷 477, 编号 1 (2017)
- 页面: 244-247
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154092
- DOI: https://doi.org/10.1134/S0012500817110040
- ID: 154092
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详细
A polyfunctional spiropyran of 1,3-benzoxazin-4-one series containing one hydroxy and two carbonyl substituents in the [2H]-chromene moiety was synthesized on the basis of a new analogue of 2,4-dihydroxyisophthalic aldehyde, methyl 3,5-diformyl-2,4-dihydroxybenzoate. The structure of resulting 6'-carbomethoxy-3,7-dimethyl-8'-formyl-5'-hydroxy-4-oxo-spiro-(1,3-benzoxazine-2,2'-[2H]-chromene) was unambiguously established by single crystal X-ray diffraction analysis. These data allowed us to reveal the route for the reaction of the new polyfunctional aldehyde with 1,3-benzoxazin-4-onium perchlorate.
作者简介
I. Ozhogin
Research Institute of Physical and Organic Chemistry
编辑信件的主要联系方式.
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Rostov-on-Don, 344090
V. Tkachev
Institute of Problems in Chemical Physics
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
B. Lukyanov
Research Institute of Physical and Organic Chemistry; Don State Technical University
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Rostov-on-Don, 344090; Rostov-on-Don, 344000
G. Shilov
Institute of Problems in Chemical Physics
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
E. Mukhanov
Research Institute of Physical and Organic Chemistry
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Rostov-on-Don, 344090
G. Vasilyuk
Yanka Kupala State University
Email: lab811@ipoc.sfedu.ru
白俄罗斯, Grodno, 230023
S. Aldoshin
Institute of Problems in Chemical Physics
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432
V. Minkin
Research Institute of Physical and Organic Chemistry
Email: lab811@ipoc.sfedu.ru
俄罗斯联邦, Rostov-on-Don, 344090