Coordination ability of N,N’-disubstituted 9,10-phenanthrenediimines

G. A. Abakumov; N. O. Druzhkov; T. N. Kocherova; K. A. Kozhanov; A. V. Murugova; E. N. Egorova

doi:10.1134/S0012500816040017

Coordination ability of N,N’-disubstituted 9,10-phenanthrenediimines

作者: Abakumov G.A.¹^,2, Druzhkov N.O.¹, Kocherova T.N.¹, Kozhanov K.A.¹, Murugova A.V.², Egorova E.N.¹
隶属关系:
1. Razyvaev Institute of Organometallic Chemistry
2. Lobachevskii State University
期: 卷 467, 编号 2 (2016)
页面: 109-112
栏目: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/153636
DOI: https://doi.org/10.1134/S0012500816040017
ID: 153636

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详细

The ability of N,N’-disubstituted 9,10-phenanthrenediimines in neutral, monoand direduced states to act as bidentate ligands in main-group-metal and transition-metal complexes has been demonstrated for the first time. The formation of metal complexes with the radical anion form of phenanthrenediimines stabilized through the formation of contact pairs (for Li) or chelate complexes (for Rh) has been detected.