Email this article Coordination ability of N,N’-disubstituted 9,10-phenanthrenediimines
- Authors: Abakumov G.A.1,2, Druzhkov N.O.1, Kocherova T.N.1, Kozhanov K.A.1, Murugova A.V.2, Egorova E.N.1
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Affiliations:
- Razyvaev Institute of Organometallic Chemistry
- Lobachevskii State University
- Issue: Vol 467, No 2 (2016)
- Pages: 109-112
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/153636
- DOI: https://doi.org/10.1134/S0012500816040017
- ID: 153636
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Abstract
The ability of N,N’-disubstituted 9,10-phenanthrenediimines in neutral, monoand direduced states to act as bidentate ligands in main-group-metal and transition-metal complexes has been demonstrated for the first time. The formation of metal complexes with the radical anion form of phenanthrenediimines stabilized through the formation of contact pairs (for Li) or chelate complexes (for Rh) has been detected.
About the authors
G. A. Abakumov
Razyvaev Institute of Organometallic Chemistry; Lobachevskii State University
Author for correspondence.
Email: ee@iomc.ras.ru
Russian Federation, ul Tropinina 49, Nizhny Novgorod, 603950; pr. Gagarina 23, Nizhny Novgorod, 603950
N. O. Druzhkov
Razyvaev Institute of Organometallic Chemistry
Email: ee@iomc.ras.ru
Russian Federation, ul Tropinina 49, Nizhny Novgorod, 603950
T. N. Kocherova
Razyvaev Institute of Organometallic Chemistry
Email: ee@iomc.ras.ru
Russian Federation, ul Tropinina 49, Nizhny Novgorod, 603950
K. A. Kozhanov
Razyvaev Institute of Organometallic Chemistry
Email: ee@iomc.ras.ru
Russian Federation, ul Tropinina 49, Nizhny Novgorod, 603950
A. V. Murugova
Lobachevskii State University
Email: ee@iomc.ras.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
E. N. Egorova
Razyvaev Institute of Organometallic Chemistry
Email: ee@iomc.ras.ru
Russian Federation, ul Tropinina 49, Nizhny Novgorod, 603950
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