Reduction of Acridine and 9-Chloroacridine with Red Phosphorus in the KOH/DMSO System


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详细

Acridine reacts with red phosphorus in the KOH/DMSO(H2O) system on heating (100°C, 3 h) to give 9,10-dihydroacridine regioselectively in quantitative yield. Under similar conditions, 9-chloroacridine reacts with Pred/KOH/DMSO(H2O) system to afford 9,10-dihydroacridine and acridone in 51 and 40% yield, respectively.

作者简介

V. Kuimov

Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

N. Gusarova

Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

S. Malysheva

Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

T. Kon’kova

Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

B. Trofimov

Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: boris_trofimov@irioch.irk.ru
俄罗斯联邦, Irkutsk, 664033

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