Email this article Electron–nuclear motions in a series of meta-substituted iodobenzene derivatives as probed by 127I NQR
- Authors: Semin G.K.1, Gushchin S.I.2, Semina E.V.1, Kuznetsov S.I.1, Burbelo V.M.1
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds
- Perm State University
- Issue: Vol 471, No 1 (2016)
- Pages: 325-329
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/153815
- DOI: https://doi.org/10.1134/S0012500816110069
- ID: 153815
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Abstract
A relation between the quadrupole coupling constant e2Qqzz and asymmetry parameter η has been found for a series of meta-substituted iodobenzene derivatives. The relationships e2Qqzz(η) for electrondonor and electron-acceptor substituents have the same form but different numerical values of parameters. The average time of full electron transfer via tunneling has been evaluated.
About the authors
G. K. Semin
Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: semin@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
S. I. Gushchin
Perm State University
Email: semin@ineos.ac.ru
Russian Federation, ul. Bukireva 15, Perm, 614990
E. V. Semina
Nesmeyanov Institute of Organoelement Compounds
Email: semin@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
S. I. Kuznetsov
Nesmeyanov Institute of Organoelement Compounds
Email: semin@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
V. M. Burbelo
Nesmeyanov Institute of Organoelement Compounds
Email: semin@ineos.ac.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
