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Vol 475, No 1 (2017)

Chemistry

N-aryl-o-iminobenzoquinones as novel regulators of radical polymerization

Grishin D.F., Vaganova L.B., Piskunov A.V., Lizyakina O.S., Chegerev M.G.

Abstract

The effect of a number of quinoid compounds on methyl methacrylate polymerization initiated by azo-bis(isobutyronitrile) has been studied. It has been revealed that N-aryl-o-iminobenzoquinones, in contrast to o-benzoquinones, can provide radical polymerization of methyl methacrylate in controllable mode. The efficiency of the compounds as chain growth regulators has been found to depend on their composition and reaction conditions. It has been established that 4,6-di-tert-butyl-N-(2,6-diethylphenyl)-o-iminobenzoquinone and 4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone under radical initiation conditions provide the synthesis of poly(methyl methacrylate) with wide-range molecular weight, retaining polydispersity indices about ~1.4–1.8 up to deep conversions.

Doklady Chemistry. 2017;475(1):149-154
pages 149-154 views

Chemical Technology

On the applicability of nanodiamonds produced by detonation synthesis for phenol testing in aqueous media

Ronzhin N.O., Puzyr A.P., Bondar V.S.

Abstract

It was found that the catalytic effect of modified nanodiamonds (MND) in the H2O2–4-aminoantipyrine–phenol oxidative azo coupling reaction is due to microimpurities of iron and copper ions on the surface of nanoparticles. The efficiency of MND as a catalyst is determined by the amount of surface impurities of these ions and can be doubled by their additional adsorption on nanoparticles. Using MND for phenol indication ensures a linear yield of the colored product of the azo coupling reaction over an analyte concentration range of 0.05–10 μg/mL. The possibility of reusing MND for phenol testing in aqueous samples was demonstrated.

Doklady Chemistry. 2017;475(1):155-158
pages 155-158 views