A New Approach to the Synthesis of Thiacrowns on a Thiacalix[4]arene Scaffold


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Abstract

A new strategy of synthesis of thiacalix[4]monothiacrown ethers in 1,3-alternate stereoisomeric form has been suggested and implemented through macrocyclization of the lower rim of 3-bromopropoxy-substituted thiacalixarenes by dithiols.

About the authors

A. A. Muravev

Arbuzov Institute of Organic and Physical Chemistry,
FRC Kazan Scientific Center, Russian Academy of Sciences

Author for correspondence.
Email: antonm@iopc.ru
Russian Federation, Kazan, 420088

A. T. Yakupov

Kazan Federal University

Email: antonm@iopc.ru
Russian Federation, Kazan, 420008

S. E. Solovieva

Arbuzov Institute of Organic and Physical Chemistry,
FRC Kazan Scientific Center, Russian Academy of Sciences; Kazan Federal University

Email: antonm@iopc.ru
Russian Federation, Kazan, 420088; Kazan, 420008

I. S. Antipin

Arbuzov Institute of Organic and Physical Chemistry,
FRC Kazan Scientific Center, Russian Academy of Sciences; Kazan Federal University

Email: antonm@iopc.ru
Russian Federation, Kazan, 420088; Kazan, 420008


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