Crystal Structure of Two-Dimensional Coordination Polymer {[Cu(dps) 2 (DMSO) 2 ](ClO 4 ) 2 }  n   Derived from 4,4'-Dipyridyl Sulfide

Yu. P. Tupolova; I. N. Shcherbakov; L. D. Popov; V. V. Tkachev; V. A. Chetverikova; G. V. Shilov; S. M. Aldoshin

doi:10.1134/S001250081812008X

Crystal Structure of Two-Dimensional Coordination Polymer {[Cu(dps)₂(DMSO)₂](ClO₄)₂}_n Derived from 4,4'-Dipyridyl Sulfide

Authors: Tupolova Y.P.¹, Shcherbakov I.N.¹, Popov L.D.¹, Tkachev V.V.², Chetverikova V.A.¹, Shilov G.V.², Aldoshin S.M.²
Affiliations:
1. Southern Federal University
2. Institute of Problems of Chemical Physics, Russian Academy of Sciences
Issue: Vol 483, No 2 (2018)
Pages: 304-307
Section: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/154325
DOI: https://doi.org/10.1134/S001250081812008X
ID: 154325

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Abstract

A new complex of general formula {[Cu(dps)₂(DMSO)₂](ClO₄)₂}_n has been obtained with the aim to study the effect of perchlorate anion on the structure of coordination polymer based on 4,4'-dipyridyl sulfide. It has been established by X-ray diffraction that the compound has a layered 2D polymer structure. Each copper(II) ion is in a pseudo-octahedral donor environment. Perchlorate anions are disposed in the network voids of the polymer complex.