An Alternative Approach to the Synthesis of Poly(naphthoylenebenzimidazole)s
- Authors: Belomoina N.M.1, Bulycheva E.G.1, Begunov R.S.2, Buzin M.I.1, Chashchin I.S.1
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds
- Demidov Yaroslavl State University
- Issue: Vol 480, No 1 (2018)
- Pages: 89-92
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154212
- DOI: https://doi.org/10.1134/S0012500818050051
- ID: 154212
Cite item
Abstract
An alternative approach to the synthesis of poly(naphthoylenebenzimidazole)s in supercritical carbon dioxide has been accomplished without use of hazardous chemical solvents, which resulted in preparation of high-purity polymers by a more efficient contemporary method. A series of poly(naphthoylenebenzimidazole) s has been obtained at 90°C and 15 MPa for 8 h with the use of a mixture of benzoic acid and benzimidazole as a catalyst. Certain properties of the synthesized polymers have been studied.
About the authors
N. M. Belomoina
Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: bel@ineos.ac.ru
Russian Federation, Moscow, 119991
E. G. Bulycheva
Nesmeyanov Institute of Organoelement Compounds
Email: bel@ineos.ac.ru
Russian Federation, Moscow, 119991
R. S. Begunov
Demidov Yaroslavl State University
Email: bel@ineos.ac.ru
Russian Federation, Yaroslavl, 150000
M. I. Buzin
Nesmeyanov Institute of Organoelement Compounds
Email: bel@ineos.ac.ru
Russian Federation, Moscow, 119991
I. S. Chashchin
Nesmeyanov Institute of Organoelement Compounds
Email: bel@ineos.ac.ru
Russian Federation, Moscow, 119991