Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type
- 作者: Kubasov A.S.1, Matveev E.Y.2, Turyshev E.S.3, Polyakova I.N.1, Bykov A.Y.1, Kopytin A.V.1, Zhizhin K.Y.1,2, Kuznetsov N.T.1
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Moscow Technological University
- Mendeleev University of Chemical Technology of Russia
- 期: 卷 483, 编号 1 (2018)
- 页面: 263-265
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154132
- DOI: https://doi.org/10.1134/S001250081811006X
- ID: 154132
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详细
New methods of creation of cyclic bridging and terminal exopolyhedral sulfur-containing substituents in the closo-decaborate anion have been suggested. It has been shown that the reaction of [B10H9SH]2– with 1,2-dibromoethane leads to crosslinking of two cluster anions to give the [B10H9S(CH2)4SB10H9]2– dimer. An analogous reaction with 1,4-dibromobutane yields a derivative with the cyclic tetrahydrothiophene substituent [B10H9S(CH2)4]–. Its interaction with tetrahydrothiophene in the presence of a small excess of trifluoroacetic acid leads to the formation of the neutral disubstituted derivative [B10H8(S(CH2)4)2].
作者简介
A. Kubasov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119991
E. Matveev
Moscow Technological University
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119571
E. Turyshev
Mendeleev University of Chemical Technology of Russia
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 125047
I. Polyakova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119991
A. Bykov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119991
A. Kopytin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119991
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Moscow Technological University
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119571
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: fobosax@mail.ru
俄罗斯联邦, Moscow, 119991
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