A new method for the synthesis of metal complexes with trans-[B20H18]2– dianion
- Авторы: Avdeeva V.V.1, Malinina E.A.1, Goeva L.V.1, Kuznetsov N.T.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Выпуск: Том 474, № 2 (2017)
- Страницы: 141-143
- Раздел: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154015
- DOI: https://doi.org/10.1134/S0012500817060052
- ID: 154015
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Аннотация
A new method has been proposed for the synthesis of transition metal complexes with the trans-[B20H18]2– dianion from complexes with the closo-decaborate anion [B10H10]2– without changing the cationic part of the complex. A cerium(IV) salt has been used as an oxidizing agent. Complexes [NiL3][trans-B20H18] (L = Bipy, Phen) have been identified by elemental analysis and IR spectroscopy.
Об авторах
V. Avdeeva
Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: avdeeva.varvara@mail.ru
Россия, Moscow, 119991
E. Malinina
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Россия, Moscow, 119991
L. Goeva
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Россия, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Россия, Moscow, 119991
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