A new method for the synthesis of metal complexes with  trans -[B 20 H 18 ] 2–  dianion

V. V. Avdeeva; E. A. Malinina; L. V. Goeva; N. T. Kuznetsov

doi:10.1134/S0012500817060052

A new method for the synthesis of metal complexes with trans-[B₂₀H₁₈]^2– dianion

Authors: Avdeeva V.V.¹, Malinina E.A.¹, Goeva L.V.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry
Issue: Vol 474, No 2 (2017)
Pages: 141-143
Section: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/154015
DOI: https://doi.org/10.1134/S0012500817060052
ID: 154015

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Abstract

A new method has been proposed for the synthesis of transition metal complexes with the trans-[B₂₀H₁₈]^2– dianion from complexes with the closo-decaborate anion [B₁₀H₁₀]^2– without changing the cationic part of the complex. A cerium(IV) salt has been used as an oxidizing agent. Complexes [NiL₃][trans-B₂₀H₁₈] (L = Bipy, Phen) have been identified by elemental analysis and IR spectroscopy.