Catalytic synthesis of  O -aryl methyl(phenyl)phosphonochloridates

V. K. Brel; E. I. Goryunov; G. N. Molchanova; I. B. Goryunova; I. Yu. Kudryavtsev; T. V. Baulina; A. A. Khodak; T. V. Strelkova; E. E. Nifant’ev

doi:10.1134/S001250081702001X

Catalytic synthesis of O-aryl methyl(phenyl)phosphonochloridates

Authors: Brel V.K.¹, Goryunov E.I.¹, Molchanova G.N.¹, Goryunova I.B.¹, Kudryavtsev I.Y.¹, Baulina T.V.¹, Khodak A.A.¹, Strelkova T.V.¹, Nifant’ev E.E.¹
Affiliations:
1. Nesmeyanov Institute of Organoelement Compounds
Issue: Vol 472, No 2 (2017)
Pages: 21-24
Section: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/153907
DOI: https://doi.org/10.1134/S001250081702001X
ID: 153907

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Abstract

The reaction of methyl- and phenyldichlorophosphonates with phenols in the presence of anhydrous magnesium chloride (catalyst) or magnesium metal (procatalyst) has been used as a simple, efficient, and industrially feasible method for the synthesis of the corresponding O-aryl alkyl(aryl)phosphonochloridates.