Inhibition of organic mechanochemical synthesis by water vapor


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The effect of water on the mechanochemical synthesis in the glycine–malonic acid system has been studied in different types of devices. Comparative studies of the hygroscopicity of the reagents and products made it possible to rationalize the inhibiting effect of water vapor and the difference in the reaction course in impact and shear devices and in devices providing both action modes. The importance of control of ambient humidity for mechanochemical reactions on the laboratory and industrial scales has been illustrated.

作者简介

I. Tumanov

Novosibirsk National Research State University; Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch

编辑信件的主要联系方式.
Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090; ul. Kutateladze 18, Novosibirsk, 630128

A. Michalchuk

Novosibirsk National Research State University

Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090

A. Politov

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch

Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Kutateladze 18, Novosibirsk, 630128

E. Boldyreva

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch

Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Kutateladze 18, Novosibirsk, 630128

V. Boldyrev

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch

Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Kutateladze 18, Novosibirsk, 630128

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