Inhibition of organic mechanochemical synthesis by water vapor
- 作者: Tumanov I.A.1,2, Michalchuk A.A.1, Politov A.A.2, Boldyreva E.V.2, Boldyrev V.V.2
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隶属关系:
- Novosibirsk National Research State University
- Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
- 期: 卷 472, 编号 1 (2017)
- 页面: 17-19
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/153902
- DOI: https://doi.org/10.1134/S0012500817010050
- ID: 153902
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详细
The effect of water on the mechanochemical synthesis in the glycine–malonic acid system has been studied in different types of devices. Comparative studies of the hygroscopicity of the reagents and products made it possible to rationalize the inhibiting effect of water vapor and the difference in the reaction course in impact and shear devices and in devices providing both action modes. The importance of control of ambient humidity for mechanochemical reactions on the laboratory and industrial scales has been illustrated.
作者简介
I. Tumanov
Novosibirsk National Research State University; Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
编辑信件的主要联系方式.
Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090; ul. Kutateladze 18, Novosibirsk, 630128
A. Michalchuk
Novosibirsk National Research State University
Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Pirogova 2, Novosibirsk, 630090
A. Politov
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Kutateladze 18, Novosibirsk, 630128
E. Boldyreva
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Kutateladze 18, Novosibirsk, 630128
V. Boldyrev
Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
Email: i.tumanov.ssc@mail.ru
俄罗斯联邦, ul. Kutateladze 18, Novosibirsk, 630128
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