Email this article Direct phosphorylation of fullerene C60 with phosphine
- Authors: Kuimov V.A.1, Matveeva E.A.1, Malysheva S.F.1, Samul’tsev D.O.1, Gusarova N.K.1, Khutsishvili S.S.1, Vakul’skaya T.I.1, Trofimov B.A.1
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Affiliations:
- Favorskii Institute of Chemistry, Siberian Branch
- Issue: Vol 471, No 1 (2016)
- Pages: 321-324
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/153812
- DOI: https://doi.org/10.1134/S0012500816110057
- ID: 153812
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Abstract
Fullerene C60 reacts with phosphine (PH3) under free radical initiation conditions (azobis(isobutyronitrile), xylene, 65°C, 6–11 h) to give in the presence of air oxygen functional oligofullerenes (yield up to 32%) containing functional groups of phosphinic and phosphonic acids.
About the authors
V. A. Kuimov
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
E. A. Matveeva
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. F. Malysheva
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
D. O. Samul’tsev
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
N. K. Gusarova
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. S. Khutsishvili
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
T. I. Vakul’skaya
Favorskii Institute of Chemistry, Siberian Branch
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
B. A. Trofimov
Favorskii Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: boris_trofimov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
