Polyarenes prepared by Suzuki–Miyaura reaction via condensation of sumanene and 3,4:9,10-perylenetetracarboxydiimide derivatives: Synthesis and chemical transformations

A. Ya. Vainer; K. M. Dyumaev; A. M. Kovalenko; T. D. Bel’skii; A. V. Vishnyakov; S. A. Krichevskaya

doi:10.1134/S0012500816100037

Polyarenes prepared by Suzuki–Miyaura reaction via condensation of sumanene and 3,4:9,10-perylenetetracarboxydiimide derivatives: Synthesis and chemical transformations

Authors: Vainer A.Y.¹, Dyumaev K.M.¹, Kovalenko A.M.¹, Bel’skii T.D.¹, Vishnyakov A.V.¹, Krichevskaya S.A.¹
Affiliations:
1. All-Russian Research Institute of Medicinal and Aromatic Plants
Issue: Vol 470, No 2 (2016)
Pages: 289-292
Section: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/153786
DOI: https://doi.org/10.1134/S0012500816100037
ID: 153786

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Abstract

A sumanene-containing polyarene with side epoxy groups has been obtained for the first time by the sequential chemical transformations of initial polyarene. The latter was prepared by the condensation of diiodosumanene and diboryl derivative of perylenetetracarboxydiimide. The epoxy-containing polyarene can provide a basis for promising negative electron resist for 12-nanometer chip manufacturing technology.