Doklady Chemistry
Doklady Chemistry is a peer-reviewed journal that publishes cutting-edge research in the fields of chemistry and chemical engineering. Doklady Chemistry is no longer solely a translation journal. It publishes manuscripts originally submitted in English and translated works. The sources of content are indicated at the article level. The peer review policy of the journal is independent of the manuscript source, ensuring a fair and unbiased evaluation process for all submissions. As part of its aim to become an international publication, the journal welcomes submissions in English from all countries.
Peer review and editorial policy
The journal follows the Springer Nature Peer Review Policy, Process and Guidance, Springer Nature Journal Editors' Code of Conduct, and COPE's Ethical Guidelines for Peer-reviewers.
Approximately 13% of the manuscripts are rejected without review based on formal criteria as they do not comply with the submission guidelines. Each manuscript is assigned to 2–3 peer reviewers. The journal follows a single-blind reviewing procedure. The period from submission to the first decision is usually at most three weeks. The approximate rejection rate is 4.5%. The final decision on the acceptance of a manuscript for publication is made by the responsible editor(s).
If Editors, including the Editor-in-Chief, publish in the journal, they do not participate in the decision-making process for manuscripts where they are listed as co-authors.
Special issues published in the journal follow the same procedures as all other issues. If not stated otherwise, special issues are prepared by the members of the editorial board without guest editors.
Current Issue
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Vol 489, No 2 (2019)
- Year: 2019
- Articles: 4
- URL: https://journals.rcsi.science/0012-5008/issue/view/9332
Chemistry
N-Heterocyclic Phosphorus Compounds Based on N,N '-Disubstituted 9,10-Phenanthrenediimines
Abstract
N-Heterocyclic phospholes based on N,N '-disubstituted 9,10-phenanthrenediimines have been synthesized for the first time. Dimeric 1,3,2-diazaphospholes have been obtained by the reduction of 2-bromodiazaphospholes. In the case of the most sterically hindered phenanthrenediimine, diphosphole can dissociate into phosphorus-centered radicals at extremely low temperatures (220 K) for this class of compounds, which makes it possible to synthesize new organophosphorus and coordination compounds under mild conditions.
279-282
Migration of Carbon Nanoparticles to the Surface of a Polymer Composite Melt
Abstract
The results of a study of migration of electrically conductive nano-sized carbon particles of different types to the surface of molten polymer composite are presented. The real-time measurements of the changes in electrical conductivity of the polymer composite melt at a constant temperature, carried out separately for the bulk and surface conductivity components, revealed the basic features of the process. The results indicate that the formation of a surface layer saturated with electrically conductive nanoparticles is a general phenomenon for composites where filler nanoparticles with different aspect ratios are used. The role of polymer macromolecules in the kinetics of migration of carbon nanoparticles to the polymer composite melt surface is discussed.
283-287
Cationic Copolymerization of Cholesterol Vinyl Ether with Methyl Vinyl Sulfide: Towards New Biologically Active Oligomers
Abstract
288-291
Chemical Technology
Distribution of TR2O3, P2O5, and Nb2O5 between Two Immiscible Melts in the Monazite–SiO2–NaF–Nb2O5–Fe2O3 System
Abstract
The monazite–SiO2–NaF–Nb2O5–Fe2O3 system in the isotherm at 1200°C is characterized by a wide region of two immiscible melts: a silicate melt and a phosphate–fluoride (salt) melt. The system is reciprocal; in the salt melt, new rare-earth metal (REM) phases form: binary phosphates and fluoride phosphates of REM and Na, which contain neither Fe, nor Nb. Iron has a strong effect on the immiscibility of the melts: in the absence of iron, the segregation region occupies 50% of the area of the diagram; at 5% Fe2O3, 57%; and at 10% Fe2O3, 70%. REM, P, and Nb oxides are contrastingly distributed between the immiscible melts. Most (95%) of REM and P are concentrated in the phosphate–salt melt, and Nb is concentrated in the iron–silicate melt. If the silicate melt contains no Fe2O3, then the Nb2O5 content is 4.91%; and at a Fe2O3 content of 15.33%, the Nb2O5 content is 6.89%, i.e. is 40% higher.
292-297