Thermochemical and Energy Characteristics of 1,4-Diethynylbenzene


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The standard enthalpy of formation of 1,4-diethynylbenzene experimentally to be 500.6 ± 6.7 kJ/mol. Calculations show that 1,4-diethynylbenzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-diethynylbenzene can be used as the basis to develop an effective dispersing agent of solid fuel that provides an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values provided by HMX and the other azides of N-heterocycles previously proposed for this purpose.

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D. Lempert

Institute of Problems of Chemical Physics

编辑信件的主要联系方式.
Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka, 142432

I. Zyuzin

Institute of Problems of Chemical Physics

Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka, 142432

A. Nabatova

Institute of Problems of Chemical Physics

Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka, 142432

A. Kazakov

Institute of Problems of Chemical Physics

Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka, 142432

L. Yanovskii

Institute of Problems of Chemical Physics

Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka, 142432

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