Stabilization of unstable detonation waves in mixtures of nitromethane with inert diluents


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Abstract

Mass velocity profiles of detonation waves in mixtures of nitromethane with acetone and methanol with added diethylenetriamine sensitizer were measured using a VISAR laser interferometer. It was found that even small, about 1%, concentrations of acetone and methanol, inert diluents, led to instability of the one-dimensional detonation front in nitromethane. The results of the experiment show that the use of the sensitizer is an effective method of flow stabilization and if the concentration of the inert diluent does not exceed 10%, the detonation front becomes stable with the addition of 1% diethylenetriamine. At a higher diluent concentration, the sensitizer does not suppress the instability but decreases the oscillation amplitude by several times. The addition of diethylenetriamine to the mixture has been found to increase the detonation velocity.

About the authors

V. M. Mochalova

Institute of Problems of Chemical Physics; Tomsk State University

Email: utkin@icp.ac.ru
Russian Federation, Chernogolovka, 142432; Tomsk, 634050

A. V. Utkin

Institute of Problems of Chemical Physics; Tomsk State University

Author for correspondence.
Email: utkin@icp.ac.ru
Russian Federation, Chernogolovka, 142432; Tomsk, 634050

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