Isomerization of n-Hexane on Pt Catalysts Deposited on Natural Montmorillonite Modified by Titanium Oxide
- Authors: Zakarina N.A.1, Kornaukhova N.A.1, Zhumadullaev D.A.1
-
Affiliations:
- D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry
- Issue: Vol 55, No 1 (2019)
- Pages: 15-23
- Section: Article
- URL: https://journals.rcsi.science/0009-3092/article/view/236147
- DOI: https://doi.org/10.1007/s10553-019-00999-6
- ID: 236147
Cite item
Abstract
Isomerization of n-hexane on Pt-catalysts supported on activated Tagan montmorillonite in the Na-form is studied as a function of the method for introducing TiO2 into the catalyst. The textural properties of the obtained catalysts and their acidic characteristics and x-ray phase and elemental compositions were determined. The isomerization properties of Pt-catalysts supported on pillared TiNaHMM and prepared by mixing TiO2 and NaHMM were compared. A simplified method was developed for preparing Pt/NaHMM + TiO2 catalyst that had stronger isomerizing activity than Pt on pillared TiNaHMM. The maximum conversion of n-hexane was shown to be 57%; maximum total yield of C6 + C7 isomers, 51.6% on Pt/NaHMM + TiO2 + HM at 400°C.
Keywords
About the authors
N. A. Zakarina
D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry
Author for correspondence.
Email: Enelly_zakarina@rambler.ru
Kazakhstan, Almaaty
N. A. Kornaukhova
D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry
Email: Enelly_zakarina@rambler.ru
Kazakhstan, Almaaty
D. A. Zhumadullaev
D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry
Email: Enelly_zakarina@rambler.ru
Kazakhstan, Almaaty