Raising the Efficiency of Antimony(III) Ion Extraction from Solutions by Modified Titanium(IV) Oxyhydroxyphosphate-Based Sorbents

A. M. Petrov; Петров А. М.; E. V. Tikhomirova; Тихомирова Е. В.; S. V. Aksenova; Аксенова С. В.; R. I. Korneikov; Корнейков Р. И.; V. I. Ivanenko; Иваненко В. И.

doi:10.31857/S0002337X23080134

Raising the Efficiency of Antimony(III) Ion Extraction from Solutions by Modified Titanium(IV) Oxyhydroxyphosphate-Based Sorbents

作者: Petrov A.M.¹, Tikhomirova E.V.¹, Aksenova S.V.¹, Korneikov R.I.¹, Ivanenko V.I.²
隶属关系:
1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials (separate subdivision), Kola Scientific Center (Federal Research Center), Russian Academy of Sciences
2. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences
期: 卷 59, 编号 8 (2023)
页面: 847-852
栏目: Articles
URL: https://journals.rcsi.science/0002-337X/article/view/231961
DOI: https://doi.org/10.31857/S0002337X23080134
EDN: https://elibrary.ru/SFGMQS
ID: 231961

如何引用文章

全文:

开放存取

##reader.subscriptionAccessGranted##
受限制的访问

订阅存取

详细
作者简介
参考
补充文件
统计

详细

We have proposed compositions of titanyl hydrogen phosphate-based sorption materials modified with zirconium(IV) cations and containing both cation and anion exchange functional centers, represented by НРО
and OH– groups, respectively. The synthesized materials were tested in sorption of antimony(III) cations and anions from high-salt solutions. Increasing the concentration of functional groups in ion exchange matrices has been shown to increase their affinity for antimony(III) ions. Such compositions can be regarded as promising ion exchange materials for efficient extraction of antimony radionuclides from multicomponent high-salt liquid radioactive waste.

关键词

liquid radioactive waste, antimony radionuclides, sorbents, modification, zirconium(IV), titanium(IV) oxyhydroxyphosphates

参考

Takahatake Y., Watanabe S., Shibata A., Nomura K., Koma Y. Decontamination of Radioactive Liquid Waste with Hexacyanoferrate(II) // Procedia Chem. 2012. № 7. P. 610–615.
Abdel-Karima A.M., Zaki A.A., Elwana W., El-Naggar M.R., Gouda M.M. Experimental and Modeling Investigations of Cesium and Strontium Adsorption onto Clay of Radioactive Waste Disposal // Appl. Clay Sci. 2016. № 132–133. P. 391–401. https://doi.org/10.1016/j.clay.2016.07.005
Mansy M.S., Hassana R.S., Selim Y.T., Kenawy S.H. Evaluation of Synthetic Aluminum Silicate Modified by Magnesia for the Removal of 137Cs, 60Co and 152+154Eu from Low-Level Radioactive Waste // Appl. Radiat. Isot. 2017. № 130. P. 198–205. https://doi.org/10.1016/j.apradiso.2017.09.042
Kong T.Y., Kim S., Lee Y., Son J.K., Maeng S.J. Radioactive Effluents Released from Korean Nuclear Power Plants and the Resulting Radiation Doses to Members of the Public // Nucl. Eng. Technol. 2017. № 49. P. 1772–1777. https://doi.org/10.1016/j.net.2017.07.021
Nishad P.A., Bhaskarapillai A., Velmurugan S. Nano-Titania-Crosslinked Chitosan Composite as a Superior Sorbent for Antimony (III) and (V) // Carbohydr. Polym. 2014. № 108. P. 169–175. https://doi.org/10.1016/j.carbpol.2014.02.091
Gil-Díaz T., Schäfer J., Pougnet F., Abdou M., Dutruch L., Eyrolle-Boyer F., Coynel A., Blanc G. Distribution and Geochemical Behaviour of Antimony in the Gironde Estuary: A First Qualitative Approach to Regional Nuclear Accident Scenarios // Mar. Chem. 2016. № 185. P. 65–73. https://doi.org/10.1016/j.marchem.2016.02.002
Remya Devi P.S., Joshi S., Verma R., Lali A.M., Gantayet L.M. Effect of Gamma Radiation on Organic Ion Exchangers // Radiat. Phys. Chem. 2010. № 79. P. 41–45.https://doi.org/10.1016/j.radphyschem.2009.08.002
Roberts C.J. Management and Disposal of Waste from Sites Contaminated by Radioactivity // Radiat. Phys. Chem. 1998. V. 51. № 4–6. P. 579–587.
Korneikov R.I., Ivanenko V.I. Extraction of Cesium and Strontium Cations from Solutions by Titanium(IV) Phosphate-Based Ion Exchangers // Inorg. Mater. 2020. V. 56. № 5. P. 502–506. https://doi.org/10.1134/S0020168520050088
Милютин В.В., Некрасова Н.А., Козлитин Е.А. Селективные неорганические сорбенты в современной прикладной радиохимии // Матер. II Всерос. науч. конф. с международным участием “Исследования и разработки в области химии и технологии функциональных материалов” Спецвыпуск отделения “Химия и материаловедение”. Апатиты: Изд-во КНЦ РАН, 2015. С. 418–421.
Korneikov R.I., Ivanenko V.I., Petrov A.M. Extraction of Antimony(III) Ions from Solutions by Sorbents Based on Titanium(IV) Compounds // Inorg. Mater. 2021. V. 57. № 5. P. 524–528. https://doi.org/10.1134/S0020168521050046
Рябчиков Б.Е. Очистка жидких радиоактивных отходов. М.: ДеЛи принт, 2008. 516 с.
Ivanenko V.I., Lokshin E.P., Korneikov R.I., Kalinnikov V.T. Increase in the Performance of Titanium Phosphate Sorbents by Modifying with Transition Metal Cations // Doklady Chemistry. 2011. V. 439. № 2. P. 230–232. https://doi.org/10.1134/S0012500811080039
Korneikov R.I., Aksenova S.V., Ivanenko V.I., Lokshin E.P. Stability of Titanyl Hydrogen Phosphates in Aqueous Media // Inorg. Mater. 2018. V. 54. № 7. P. 689–693. https://doi.org/10.1134/S0020168518070063
Ivanenko V.I., Korneikov R.I., Lokshin E.P. Immobilization of Metal Cations with Titanium PhosphatE Sorbents // Radiochemistry. 2016. V. 58. № 2. P. 159–166. https://doi.org/10.1134/S1066362216020089