Adhesion Strength of the Interface between Solid Phases in the GaxGe40–xS60–Quartz Glass System

S. V. Mishinov; Мишинов С. В.; E. A. Tyurina; Тюрина Е. А.; A. P. Velmuzhov; Вельмужов А. П.; M. V.  Sukhanov; Суханов М. В.; A. D. Plekhovich; Плехович А. Д.; B. S. Stepanov; Степанов Б. С.; V. S. Shiryaev; Ширяев В. С.

doi:10.31857/S0002337X23020124

Adhesion Strength of the Interface between Solid Phases in the GaxGe40–xS60–Quartz Glass System

Authors: Mishinov S.V.¹, Tyurina E.A.¹, Velmuzhov A.P.¹, Sukhanov M.V.¹, Plekhovich A.D.¹, Stepanov B.S.¹, Shiryaev V.S.¹
Affiliations:
1. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia
Issue: Vol 59, No 2 (2023)
Pages: 191-196
Section: Articles
URL: https://journals.rcsi.science/0002-337X/article/view/140132
DOI: https://doi.org/10.31857/S0002337X23020124
EDN: https://elibrary.ru/YEGUOX
ID: 140132

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Abstract
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Abstract

Using normal pull-off testing, we have studied adhesion contact strength in the GaxGe40–xS60–quartz glass system as a function of contact formation temperature, pull-off test temperature, and chalcogenide glass composition. The addition of 1 at % gallium to glass composition considerably reduces the adhesion strength. Further increasing the percentage of gallium, to 8 at %, causes only a slight drop in adhesion. The observed general relationships can be accounted for by partial glass crystallization on heating for adhesion contact formation and subsequent cooling to the pull-off test temperature. We have formulated recommendations concerning detachment of GaxGe40–xS60 glasses from the quartz reactor wall.

Keywords

chalcogenide glass, quartz glass, adhesion strength

References

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