Preparation and Properties of Glasses in the Tellurium Dioxide–Sodium Hexametaphosphate System

E. L. Tikhonova; Тихонова Е. Л.; A. V. Markin; Маркин А. В.; I. A. Grishin; Гришин И. А.; A. P. Savikin; Савикин А. П.

doi:10.31857/S0002337X2302015X

Preparation and Properties of Glasses in the Tellurium Dioxide–Sodium Hexametaphosphate System

Authors: Tikhonova E.L.¹, Markin A.V.¹, Grishin I.A.¹, Savikin A.P.¹
Affiliations:
1. Lobachevsky State University (National Research University), 603195, Nizhny Novgorod, Russia
Issue: Vol 59, No 2 (2023)
Pages: 185-190
Section: Articles
URL: https://journals.rcsi.science/0002-337X/article/view/140130
DOI: https://doi.org/10.31857/S0002337X2302015X
EDN: https://elibrary.ru/YFCMYM
ID: 140130

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Abstract
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Abstract

New glasses in the TeO2–Na6P6O18 system have been prepared, their thermal behavior has been studied by differential scanning calorimetry in the range 25–580°C, and their heat capacity has been determined as a function of temperature in the range 25–400°C. We have evaluated characteristics of the devitrification process and glassy state, obtained analytical representations of the glass transition temperature and the thermodynamic characteristics of the glasses as functions of their composition at 80°C, and carried out a comparative analysis of the results together with those for previously studied TeO2-based binary systems. Optical transmission of the glasses has been measured in the UV, visible, and IR spectral regions. We have demonstrated the possibility of doping the glasses with rare-earth oxides and studied luminescence properties of the glass with the composition 0.89TeO2–0.08Na6P6O18–0.03Nd2O3.

Keywords

glass, tellurium dioxide, sodium hexametaphosphate, glass transition, heat capacity, calorimetry, transmission spectrum, luminescence

References

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