Sulfate Sources in Carbonaceous Aerosol Particles in the Urban Atmosphere: The Case of Irkutsk
- Авторы: Yermakov A.1, Aloyan A.2, Arutyunyan V.2
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Учреждения:
- Talroze Institute for Energy Problems of Chemical Physics, Russian Academy of Sciences
- Institute of Numerical Mathematics, Russian Academy of Sciences
- Выпуск: Том 55, № 3 (2019)
- Страницы: 271-280
- Раздел: Article
- URL: https://journals.rcsi.science/0001-4338/article/view/148715
- DOI: https://doi.org/10.1134/S0001433819020051
- ID: 148715
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Аннотация
According to monitoring data, it is found that the main source of sulfates in carbonaceous particles in the atmosphere of Irkutsk is sulfur dioxide captured from the air. Their accumulation in the particles is caused by heterogeneous chemical reactions (HCRs) and is accompanied by the substitution of hydrocarbonates (\({\text{HCO}}_{3}^{ - }\)) for sulfate anions. In this case, sulfur dioxide is oxidized by ozone in the dry atmosphere, and hydrogen peroxide (H2O2), along with dissolved ozone, also participates in the oxidation process in the moist atmosphere. The details of the mechanisms for these HСRs are discussed and the estimates of the dynamics of sulphate production in carbonaceous particles are indicated.
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Об авторах
A. Yermakov
Talroze Institute for Energy Problems of Chemical Physics, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: polclouds@yandex.ru
Россия, Moscow, 119334
A. Aloyan
Institute of Numerical Mathematics, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: aloyan@inm.ru
Россия, Moscow, 119333
V. Arutyunyan
Institute of Numerical Mathematics, Russian Academy of Sciences
Email: aloyan@inm.ru
Россия, Moscow, 119333