Transformations of Ethanol on Catalysts Based on Nanoporous Calcium Aluminate–Mayenite (Ca12Al14O33) and Mayenite Doped by Copper


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Catalytic properties of nondoped and copper-doped Mayenite have been studied. During ethanol conversion and ethanol steam reforming, the initial Mayenite and specimens containing 0.58 and 0.92 wt % of copper have been analyzed. All catalysts are active in both processes. The influence of the ethanol/water mole ratio on product distribution has been studied. In the course of experiments, the fact of reversible hydrogen sorption has been detected upon the thermal treatment of catalysts containing copper.

Sobre autores

E. Mironova

Topchiev Institute of Petrochemical Synthesis

Autor responsável pela correspondência
Email: palukas@ips.ac.ru
Rússia, Moscow, 119991

M. Ermilova

Topchiev Institute of Petrochemical Synthesis

Email: palukas@ips.ac.ru
Rússia, Moscow, 119991

N. Orekhova

Topchiev Institute of Petrochemical Synthesis

Email: palukas@ips.ac.ru
Rússia, Moscow, 119991

A. Tolkacheva

Institute of High Temperature Electrochemistry, Ural Branch; Institute of New Materials and Technologies

Email: palukas@ips.ac.ru
Rússia, Yekaterinburg, 620090; Yekaterinburg, 620078

S. Shkerin

Institute of High Temperature Electrochemistry, Ural Branch

Email: palukas@ips.ac.ru
Rússia, Yekaterinburg, 620090

A. Yaroslavtsev

Topchiev Institute of Petrochemical Synthesis; Kurnakov Institute of General and Inorganic Chemistry

Email: palukas@ips.ac.ru
Rússia, Moscow, 119991; Moscow, 119991

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