Radiation-chemical synthesis of silver nanoparticles in aqueous solution of chitin derivative


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It has been demonstrated for the first time that, in the process of gamma-induced reduction of Ag+ in aqueous solution of biodegradable carboxymethyl chitin (CMC) polyelectrolyte, a metal-polymer colloidal solution is formed, wherein silver nanoparticles have spherical shape and a size of about 1–5 nm. By using UV–Vis spectroscopy and transmission electron microscopy (TEM), the influence of CMC concentration and radiation doses on the formation of clusters and silver nanoparticles in the metal-polymer colloidal solution is observed. Colloidal solutions of silver nanoparticles in CMC exhibit a clear concentration-dependent bactericidal activity toward the strains of Gram-positive Staphilococcus aureus, as well as Gram-negative Salmonella tythimurium bacteria.

作者简介

L. Shirokova

Topchiev Institute of Petrochemical Synthesis

编辑信件的主要联系方式.
Email: shirokova@ips.ac.ru
俄罗斯联邦, Leninskii pr. 29, Moscow, 119991

A. Revina

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: shirokova@ips.ac.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119071

V. Aleksandrova

Topchiev Institute of Petrochemical Synthesis

Email: shirokova@ips.ac.ru
俄罗斯联邦, Leninskii pr. 29, Moscow, 119991

A. Fenin

Mendeleyev University of Chemical Technology of Russia

Email: shirokova@ips.ac.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047

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