The Influence of High Reactivity of Diaryl Telluroxides on Their Chromatography/Mass Spectrometry Identification Data


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The identification features of symmetric and nonsymmetric diaryl telluroxides via chromatography/mass spectrometry with electrospray ionization (HPLC/MS-ESI) are studied in the present work. Diaryl telluroxides exposed to ESI are shown to give rise to the formation of dimer ions and associate ions with the mobile phase components. Moreover, the influence of analyte concentration in the solution and the injection volume is found to impact the chromatography/mass spectrometry data.

Sobre autores

E. Eliseeva

Korolev Samara National Research University

Autor responsável pela correspondência
Email: eveletskaya@gmail.com
Rússia, Samara, 443086

N. Red’kin

Korolev Samara National Research University

Email: eveletskaya@gmail.com
Rússia, Samara, 443086

V. Gar’kin

Korolev Samara National Research University

Email: eveletskaya@gmail.com
Rússia, Samara, 443086

I. Pytskii

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: eveletskaya@gmail.com
Rússia, Moscow, 119071

A. Buryak

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: eveletskaya@gmail.com
Rússia, Moscow, 119071

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