Effect of the structure of the oxidized titanium surface on the particle size and properties of the deposited copper–molybdate catalyst


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The parameters of wetting of oxide coatings on titanium formed by the method of plasma electrolytic oxidation (PEO) in an aqueous silicate electrolyte with subsequent deposition of a layer of TiO2 nanoparticles and ultrasonic treatment by a polymer–salt gel including copper and molybdenum compounds have been investigated. The effect of the oxidized surface microrelief, TiO2 nanoparticle layer, and pore shape and size on impregnation solution spreading and the structure of the copper–molybdenum catalytic coating formed at further thermal treatment has been demonstrated. Complex oxide composites with ultradispersed catalyst particle sizes characterized with high activity in oxidation of carbon black particles have been obtained.

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N. Lebukhova

Institute of Materials, Khabarovsk Scientific Centre, Far Eastern Branch

编辑信件的主要联系方式.
Email: lnv1@yandex.ru
俄罗斯联邦, Khabarovsk

V. Rudnev

Institute of Chemistry, Far-Eastern Branch; Far Eastern Federal University

Email: lnv1@yandex.ru
俄罗斯联邦, pr. 100-letya Vladivostoka 159, Vladivostok, 690022; ul. Sukhanova 8, Vladivostok, 690950

E. Kirichenko

Institute of Materials, Khabarovsk Scientific Centre, Far Eastern Branch

Email: lnv1@yandex.ru
俄罗斯联邦, Khabarovsk

P. Chigrin

Institute of Materials, Khabarovsk Scientific Centre, Far Eastern Branch

Email: lnv1@yandex.ru
俄罗斯联邦, Khabarovsk

I. Lukiyanchuk

Institute of Chemistry, Far-Eastern Branch

Email: lnv1@yandex.ru
俄罗斯联邦, pr. 100-letya Vladivostoka 159, Vladivostok, 690022

T. Yarovaya

Institute of Chemistry, Far-Eastern Branch

Email: lnv1@yandex.ru
俄罗斯联邦, pr. 100-letya Vladivostoka 159, Vladivostok, 690022

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