Synthesis and Characterization of Carbon Steel Corrosion Inhibitors Based on 4,5,6,7-tetrahydrobenzo[b]thiophene Scaffold
- Authors: Bahaa El-Dien M. El-Gendy 1, Atwa S.T.1, Ahmed A.A.1, El-Etre A.Y.1
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Affiliations:
- Chemistry Department, Faculty of Science, Benha University
- Issue: Vol 55, No 1 (2019)
- Pages: 179-186
- Section: Physicochemical Problems of Materials Protection
- URL: https://journals.rcsi.science/2070-2051/article/view/204881
- DOI: https://doi.org/10.1134/S2070205119010106
- ID: 204881
Cite item
Abstract
Three novel inhibitors based on 4,5,6,7-tetrahydrobenzo[b]thiophene scaffold were synthesized and characterized. The inhibitive action of the synthesized inhibitors toward carbon steel acid corrosion was investigated using weight loss and polarization techniques. It was found that the three compounds act as good corrosion inhibitor for carbon steel in the acidic medium. The inhibition efficiency was found to increase with increasing concentration and decreased with increasing temperature. The adsorption of inhibitors molecules on the carbon steel surface follows Langmuir adsorption isotherm. The correlation between the inhibitors structures and their corrosion inhibition action was studied by quantum chemical calculations.
Keywords
About the authors
Bahaa El-Dien M. El-Gendy
Chemistry Department, Faculty of Science, Benha University
Author for correspondence.
Email: belgendy@fsc.bu.edu.eg
Egypt, Benha, 13518
Shoukar T. Atwa
Chemistry Department, Faculty of Science, Benha University
Email: belgendy@fsc.bu.edu.eg
Egypt, Benha, 13518
Aziza A. Ahmed
Chemistry Department, Faculty of Science, Benha University
Email: belgendy@fsc.bu.edu.eg
Egypt, Benha, 13518
Ali Y. El-Etre
Chemistry Department, Faculty of Science, Benha University
Email: belgendy@fsc.bu.edu.eg
Egypt, Benha, 13518
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