Description of Adsorption-Stimulated Deformation of Microporous Adsorbents Based on Generalized Potential of Intermolecular Interactions (6, n)


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A semiempirical method based on a generalized potential of intermolecular interactions (6, n) was developed to describe adsorption-stimulated deformation of microporous adsorbents. The calculations have been carried out for such adsorption systems as “microporous carbon adsorbent—methane” and “zeolite—NaX—Xe” in the temperature interval from 178 up to 393 K and at pressures ranging from 1 Pa to 6 MPa. The equations agreed qualitatively with experimental data.

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A. Shkolin

Frumkin Institute of Physical Chemistry and Electrochemistry; Ltd AKELA-N Michurinskii Pervyi tupik 20

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Email: shkolin@bk.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 199071; Khimki, Moscow oblast, 141420

A. Fomkin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: shkolin@bk.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 199071

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