Hydroprocessing of straight run diesel mixed with light cycle oil from fluid catalytic cracking, using sulfide NiMo catalyst on zeolite-containing supports

Resumo

It is proposed that the sulfide NiMo system supported on alumina-SAPO-31 composite (NiMo/Al₂O₃-SAP catalyst) be used to obtain high-quality diesel fuel from a mixture of straight run diesel (SRGO) and light cycle oil (LCO) produced by fluid catalytic cracking (FCC). It is shown that the use of this catalyst ensures the synthesis of diesel fuel of higher quality upon hydroprocessing a feedstock with 30 wt % LCO, compared to the traditional sulfide NiMo/Al₂O₃ or CoMo/Al₂O₃ catalysts. It is found that the content of aliphatic hydrocarbons is raised in the products of hydrotreatment, compared to the initial feedstock. This confirms the ability of NiMo/Al₂O₃-SAP catalyst to facilitate the reaction of ring opening. Using the proposed catalyst should improve the quality of diesel fuels obtained via the hydroprocessing of LCO-containing feedstock.