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Ammonia decomposition on a platinum nanocoating at various electric potentials


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Resumo

It was shown that the rate of ammonia decomposition on a platinum nanocoating can be controlled by applying an external electrostatic field to the coating to create a negative or positive platinum potential of variable magnitude. In experiments conducted with a contact time of 15 min between platinum and ammonia at a temperature of 700 K and a pressure of 5 × 10–7 Torr, the decomposition rate increased by 44% at a negative potential of the coating of–6 V and by 70% at a positive potential of +6 V.

Sobre autores

M. Grishin

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Rússia, Moscow

A. Gatin

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Rússia, Moscow

V. Slutskii

Semenov Institute of Chemical Physics

Autor responsável pela correspondência
Email: slutsky@center.chph.ras.ru
Rússia, Moscow

V. Kharitonov

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Rússia, Moscow

S. Tsyganov

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Rússia, Moscow

B. Shub

Semenov Institute of Chemical Physics

Email: slutsky@center.chph.ras.ru
Rússia, Moscow

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Declaração de direitos autorais © Pleiades Publishing, Ltd., 2016