Fabrication of supporting electrolytes based on samarium doped cerium oxide by hybrid inkjet printing

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In this work, the supporting electrolytes for solid oxide fuel cells based on samarium doped cerium oxide Ce0.8Sm0.2O1.95 were fabricated using 3D inkjet printing and layer-by-layer laser treatment followed by thermal sintering. The samples were characterized by scanning electron microscopy, X-ray diffraction analysis and impedance spectroscopy. The Vickers hardness test and three-point bending flexural test were carried out. The developed approach allows for precise control of the layer thickness and microstructure, significantly facilitating the scaling of solid oxide fuel cells production, and reducing the loss of expensive ceramic materials.

作者简介

Inna Malbakhova

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0003-4193-3571
18, Kutateladze St., Novosibirsk, 630128

Artem Bagishev

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0003-2634-3653
18, Kutateladze St., Novosibirsk, 630128

Alexander Vorobyev

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0002-4896-3821
18, Kutateladze St., Novosibirsk, 630128

Tatyana Borisenko

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0003-0341-8755
18, Kutateladze St., Novosibirsk, 630128

Artem Ulihin

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0002-6795-0006
SPIN 代码: 2810-7309
Scopus 作者 ID: 15046088200
Researcher ID: P-1187-2017
18, Kutateladze St., Novosibirsk, 630128

Alexander Titkov

Institute of Chemistry of a Solid body and Mechanochemistry of the Siberian Branch of RAS

ORCID iD: 0000-0003-0835-9985
18, Kutateladze St., Novosibirsk, 630128

参考

  1. Filippov S. P., Yaroslavtsev A. B. Hydrogen energy: Development prospects and materials. Russ. Chem. Rev., 2021, vol. 90, pp. 627–643. https://doi.org/10.1070/RCR5014
  2. Minary-Jolandan M. Formidable Challenges in Additive Manufacturing of Solid Oxide Electrolyzers (SOECs) and Solid Oxide Fuel Cells (SOFCs) for Electrolytic Hydrogen Economy toward Global Decarbonization. Ceramics, 2022, vol. 5, pp. 761–779. https://doi.org/10.3390/ceramics5040055
  3. Han G. D., Bae K., Kang E. H., Choi H. J., Shim J. H. Inkjet printing for manufacturing solid oxide fuel cells. ACS Energy Lett., 2020, vol. 5, iss. 5, pp. 1586–1592. https://doi.org/10.1021/acsenergylett.0c00721
  4. Li W., Wang M., Ma H., Chapa-Villarreal F. A., Lobo A. O., Zhang Y. S. Stereolithography apparatus and digital light processing-based 3D bioprinting for tissue fabrication. iScience, 2023, vol. 26, iss. 2, article no. 106039. https://doi.org/10.1016/j.isci.2023.106039
  5. Malbakhova I., Bagishev A., Vorobyev A., Borisenko T., Logutenko O., Lapushkina E., Titkov A. An Anode-Supported Solid Oxide Fuel Cell (SOFC) Half-Cell Fabricated by Hybrid 3D Inkjet Printing and Laser Treatment. Ceramics, 2023, vol. 6, iss. 3, pp. 1384–1396. https://doi.org/10.3390/ceramics6030085
  6. Malbakhova I. A., Bagishev A. S., Vorobyev A. M., Borisenko T. A., Titkov A. I. The Effect of the Pore Former Nature on the Microstructure of Solid-Oxide-Fuel-Cell NiO- and 10YSZBased Anodes Formed by Hybrid 3D-Printing. Russ. J. Electrochem., 2024, vol. 60, iss. 3, pp. 191–199. https://doi.org/10.1134/s102319352403008x
  7. Ruifeng G., Zongqiang M. Sintering of Ce0.8Sm0.2O1.9. Journal of Rare Earths, 2007, vol. 25, iss. 3, pp. 364–367. https://doi.org/10.1016/S1002-0721(07)60437-2

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