Effect of Bonding Scandium(III) ion to 1,3-Diketones on Their Luminescent Properties


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We study the influence of bonding Sc(III) ion with 1,3-diketonate ligands on luminescent properties of 1,3-diketones in two complexes by means of optical spectroscopy. We show that the sensitization of the ligand luminescence of the complexes obtained increases from 0.8% for neat ligands and to 4% for the synthesized compounds; this fact is confirmed by the quantum yield measurements.

作者简介

A. Vitukhnovsky

Lebedev Physical Institute, Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University)

Email: vladkorshunov@bk.ru
俄罗斯联邦, Leninskii Prospect 53, Moscow, 119991; Institutskii per. 9, Moscow Region, Dolgoprudny, 141700

S. Ambrozevich

Lebedev Physical Institute, Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University); Bauman Moscow State Technical University

Email: vladkorshunov@bk.ru
俄罗斯联邦, Leninskii Prospect 53, Moscow, 119991; Institutskii per. 9, Moscow Region, Dolgoprudny, 141700; The 2nd Baumanskaya Street 5, Moscow, 105005

V. Korshunov

Lebedev Physical Institute, Russian Academy of Sciences; Bauman Moscow State Technical University

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Email: vladkorshunov@bk.ru
俄罗斯联邦, Leninskii Prospect 53, Moscow, 119991; The 2nd Baumanskaya Street 5, Moscow, 105005

I. Taydakov

Lebedev Physical Institute, Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University)

Email: vladkorshunov@bk.ru
俄罗斯联邦, Leninskii Prospect 53, Moscow, 119991; Institutskii per. 9, Moscow Region, Dolgoprudny, 141700

M. Metlin

Lebedev Physical Institute, Russian Academy of Sciences

Email: vladkorshunov@bk.ru
俄罗斯联邦, Leninskii Prospect 53, Moscow, 119991

A. Selyukov

Lebedev Physical Institute, Russian Academy of Sciences; Moscow Institute of Physics and Technology (State University)

Email: vladkorshunov@bk.ru
俄罗斯联邦, Leninskii Prospect 53, Moscow, 119991; Institutskii per. 9, Moscow Region, Dolgoprudny, 141700

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