Impact of γ-Irradiation on the Kinetics of Laser Ablation of Polyamide Under Continuous CO2 Laser Beam


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Abstract

The effect of preliminary γ-irradiation on accelerating the speed of laser ablation of a polyamide is measured for the first time. A linear increase of intensity with a rate of 0.15 mg/s is observed during laser ablation of the polyamide pre-irradiated with γ-rays at a dose of 3,500 kGy. A γ-radiolysis dose of 10 – 20 kGy causes extreme changes in the molecular-topological parameters and the maximum level of growth of the rate of laser ablation. Thus pre-irradiation with γ-rays may be used to optimize the laser ablation of the polymer.

About the authors

I. A. Frolov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: dadixon@ua.edu
Russian Federation, Chernogolovka, Moscow Region, 142432

S. R. Allayarov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: dadixon@ua.edu
Russian Federation, Chernogolovka, Moscow Region, 142432

L. A. Kalinin

V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus

Email: dadixon@ua.edu
Belarus, Gomel, 246050

D. A. Dixon

Department of Chemistry, The University of Alabama

Author for correspondence.
Email: dadixon@ua.edu
United States, Tuscaloosa, AL, 35487-0336

E. M. Tolstopyatov

V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus

Email: dadixon@ua.edu
Belarus, Gomel, 246050

P. N. Grakovich

V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus

Email: dadixon@ua.edu
Belarus, Gomel, 246050

L. F. Ivanov

V. A. Belyi Metal-Polymer Research Institute, National Academy of Sciences of Belarus

Email: dadixon@ua.edu
Belarus, Gomel, 246050

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