Reaction of 3,4,6-trioxoalkanoic acid esters with 2,4-dinitrophenylhydrazine


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Resumo

Methyl 3,4,6-trioxoalkanoates (3,4-dihydroxy-6-oxo-2,4-alkadienoates) reacted with 2,4-dinitrophenylhydrazine to give methyl 3,6-bis[(2,4-dinitrophenyl)hydrazinylidene]-4-oxoalkanoates or methyl {5-alkyl-2-hydroxy-1-(2,4-dinitroanilino)-3-oxo-2,3-dihydro-1H-pyrrol-2-yl }acetates. Alkyl 3,6-bis[(2,4-dinitrophenyl) hydrazinylidene]-4-oxoalkanoates were also synthesized by reaction of disodium 1-alkoxy-1,6-dioxoalka-2,4-diene-3,4-diolates with 2,4-dinitrophenylhydrazine.

Sobre autores

P. Mukovoz

Orenburg Branch

Autor responsável pela correspondência
Email: mpp27@mail.ru
Rússia, pr. Pobedy 75, Orenburg, 460018

A. Gorbunova

Orenburg State University

Email: mpp27@mail.ru
Rússia, pr. Pobedy 13, Orenburg, 460018

P. Slepukhin

Postovskii Institute of Organic Synthesis, Ural Branch; Yeltsin Ural Federal University

Email: mpp27@mail.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990; ul. Mira 19, Yekaterinburg, 620990

O. El’tsov

Yeltsin Ural Federal University

Email: mpp27@mail.ru
Rússia, ul. Mira 19, Yekaterinburg, 620990

I. Ganebnykh

Postovskii Institute of Organic Synthesis, Ural Branch; Yeltsin Ural Federal University

Email: mpp27@mail.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990; ul. Mira 19, Yekaterinburg, 620990

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