Отправить статью по E-mail Reactions of aromatic compounds with xenon difluoride
- Авторы: Bardin V.V.1,2, Adonin N.Y.2,3
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Учреждения:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk State University
- Boreskov Institute of Catalysis, Siberian Branch
- Выпуск: Том 52, № 10 (2016)
- Страницы: 1400-1407
- Раздел: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/215018
- DOI: https://doi.org/10.1134/S1070428016100055
- ID: 215018
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Аннотация
Reactions of substituted benzenes C6H5R (R = Me, F, Cl, Br, CF3, NO2) with xenon difluoride in the presence of boron trifluoride–diethyl ether complex in weakly acidic (1,1,1,3,3-pentafluorobutane) and weakly basic media (acetonitrile) have been studied. These reactions lead to the formation of fluorobenzene derivatives FC6H4R (isomer mixture) together with isomeric difluorobenzenes and fluorinated and non-fluorinated biphenyls. The results have been compared with previously reported data obtained in other solvents using other catalysts.
Об авторах
V. Bardin
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk State University
Email: adonin@catalysis.ru
Россия, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
N. Adonin
Novosibirsk State University; Boreskov Institute of Catalysis, Siberian Branch
Автор, ответственный за переписку.
Email: adonin@catalysis.ru
Россия, ul. Pirogova 2, Novosibirsk, 630090; pr. Akad. Lavrent’eva 5, Novosibirsk, 630090
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