Synthesis of Pyrrole Derivatives Promoted by Fe(ClO4)3/SiO2 as an Environmentally Friendly Catalyst


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Аннотация

N-Substituted pyrroles have been prepared in high isolated yields (702-99%) by the reaction of hexane-2,5-dione with amines or diamines in the presence of Fe(ClO4)3/SiO2 at ambient temperature under solvent-free conditions. The experimental procedure involves simple operations, and the products are readily separated by short column chromatography. The same reaction of hexane-2,5-dione with amines containing electron-acceptor substituents, such as 4-nitroaniline, resulted in fair yields of pyrrole derivatives.

Авторлар туралы

K. Arabpourian

Department of Chemistry, Karaj Branch

Email: Farahnazkargar@yahoo.com
Иран, Karaj

F. Behbahani

Department of Chemistry, Karaj Branch

Хат алмасуға жауапты Автор.
Email: Farahnazkargar@yahoo.com
Иран, Karaj

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