Email this article Arylation of adamantanamines: IX. Copper(I)-catalyzed arylation of adamantane-containing amines
- Authors: Averin A.D.1,2, Panchenko S.P.1, Abel A.S.1, Maloshitskaya O.A.1, Butov G.M.3, Savelyev E.N.4, Orlinson B.S.4, Novakov I.A.4, Beletskaya I.P.1,2
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Affiliations:
- Faculty of Chemistry
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Volzhskii Polytechnic Institute
- Volgograd State Technical University
- Issue: Vol 53, No 12 (2017)
- Pages: 1788-1798
- Section: Article
- URL: https://journals.rcsi.science/1070-4280/article/view/217012
- DOI: https://doi.org/10.1134/S1070428017120028
- ID: 217012
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Abstract
Copper(I)-catalyzed arylation of 14 adamantane-containing amines with iodobenzene, 1-fluoro-4-iodobenzene, 1-iodo-4-(trifluoromethyl)benzene, and 1-iodo-4-methoxybenzene has been studied under the conditions optimized previously. The yields of the N-arylation products have been shown to depend in a complicated manner on the amine structure, steric environment of the amino group, and substituent nature in iodobenzene.
About the authors
A. D. Averin
Faculty of Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: averin@org.chem.msu.ru
Russian Federation, Leninskie gory 1, Moscow, 119991; Leninskii pr. 31-4, Moscow, 119071
S. P. Panchenko
Faculty of Chemistry
Email: averin@org.chem.msu.ru
Russian Federation, Leninskie gory 1, Moscow, 119991
A. S. Abel
Faculty of Chemistry
Email: averin@org.chem.msu.ru
Russian Federation, Leninskie gory 1, Moscow, 119991
O. A. Maloshitskaya
Faculty of Chemistry
Email: averin@org.chem.msu.ru
Russian Federation, Leninskie gory 1, Moscow, 119991
G. M. Butov
Volzhskii Polytechnic Institute
Email: averin@org.chem.msu.ru
Russian Federation, ul. Engel’sa 42a, Volzhskii, Volgograd oblast, 404121
E. N. Savelyev
Volgograd State Technical University
Email: averin@org.chem.msu.ru
Russian Federation, pr. imeni Lenina 28, Volgograd, 400005
B. S. Orlinson
Volgograd State Technical University
Email: averin@org.chem.msu.ru
Russian Federation, pr. imeni Lenina 28, Volgograd, 400005
I. A. Novakov
Volgograd State Technical University
Email: averin@org.chem.msu.ru
Russian Federation, pr. imeni Lenina 28, Volgograd, 400005
I. P. Beletskaya
Faculty of Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: averin@org.chem.msu.ru
Russian Federation, Leninskie gory 1, Moscow, 119991; Leninskii pr. 31-4, Moscow, 119071
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