Synthesis, structure, and photoluminescence properties of bis[2-(1,3-benzoxazol-2-yl-κ N )-4,5-dichloro-3-(ethoxycarbonyl)phenolato-κ O ]zinc(II)

Yu. A. Sayapin; S. A. Nikolaevskii; N. I. Makarova; E. A. Gusakov; I. O. Tupaeva; I. V. Dorogan; A. V. Metelitsa; V. I. Minkin

doi:10.1134/S1070428016070162

Synthesis, structure, and photoluminescence properties of bis[2-(1,3-benzoxazol-2-yl-κN)-4,5-dichloro-3-(ethoxycarbonyl)phenolato-κO]zinc(II)

Authors: Sayapin Y.A.¹^,2, Nikolaevskii S.A.³, Makarova N.I.², Gusakov E.A.², Tupaeva I.O.², Dorogan I.V.², Metelitsa A.V.², Minkin V.I.¹^,2
Affiliations:
1. Southern Scientific Center
2. Institute of Physical and Organic Chemistry
3. Kurnakov Institute of General and Inorganic Chemistry
Issue: Vol 52, No 7 (2016)
Pages: 1018-1021
Section: Article
URL: https://journals.rcsi.science/1070-4280/article/view/214711
DOI: https://doi.org/10.1134/S1070428016070162
ID: 214711

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Abstract

The structure of bis[2-(1,3-benzoxazol-2-yl-κN)-4,5-dichloro-3-(ethoxycarbonyl)phenolato-κO]-zinc(II) was determined by IR and ¹H and ¹³C NMR spectroscopy, and its structural characteristics were estimated by quantum chemical calculations. The complex showed photoluminescence properties.

About the authors

Yu. A. Sayapin

Southern Scientific Center; Institute of Physical and Organic Chemistry

Author for correspondence.
Email: sayapin@ipoc.rsu.ru
Russian Federation, ul. Chekhova 41, Rostov-on-Don, 344006; pr. Stachki 194/2, Rostov-on-Don, 344090

S. A. Nikolaevskii

Kurnakov Institute of General and Inorganic Chemistry

Email: sayapin@ipoc.rsu.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991