Thermal decomposition study of chloride-containing complex ammonium nitrate-based fertilizers by thermogravimetry and differential scanning calorimetry


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Thermogravimetry and differential scanning calorimetry were used to study the thermal properties of chloride-containing complex ammonium nitrate-based fertilizers produced with various degrees of phosphoric acid ammonization on the basis of ammonium nitrate. Isoconversion integral methods were used to calculate the dependence of the activation energy on the degree of exothermic decomposition. It was shown that the exothermic decomposition process occurs in several stages. A conclusion was made on the basis of the results obtained that the thermal decomposition of these types of fertilizers is affected by the degree of ammonization and by the component ratio.

作者简介

K. Gorbovskiy

The Research Institute for Fertilizers and Insecto-Fungicides Named after Professor Y. Samoilov

编辑信件的主要联系方式.
Email: sulfur32@bk.ru
俄罗斯联邦, Severnoe sh. 75, Cherepovets, 162622

A. Kazakov

Institute of Problems of Chemical Physics

Email: sulfur32@bk.ru
俄罗斯联邦, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

A. Norov

The Research Institute for Fertilizers and Insecto-Fungicides Named after Professor Y. Samoilov

Email: sulfur32@bk.ru
俄罗斯联邦, Severnoe sh. 75, Cherepovets, 162622

D. Pagaleshkin

The Research Institute for Fertilizers and Insecto-Fungicides Named after Professor Y. Samoilov

Email: sulfur32@bk.ru
俄罗斯联邦, Severnoe sh. 75, Cherepovets, 162622

A. Mikhaylichenko

Mendeleev University of Chemical Technology of Russia

Email: sulfur32@bk.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047

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