A new approach to preparation of granulated materials based on chitosan and its imidazole derivative


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Abstract

A new approach to preparation of granulated materials based on chitosan and N-(5-methyl-4-imidazolyl)- methyl chitosan was developed. The procedure is simple and efficient and involves the use of glutaraldehyde as cross-linking agent without using precipitants. The composition and structural features of the materials obtained were determined by elemental analysis and Fourier IR spectroscopy. The dependence of the degree of material swelling on the degree of functionalization with glutaraldehyde was determined. The polymer granules were used as support for Pd0-containing catalysts for reduction of organic compounds.

About the authors

A. V. Pestov

Postovskii Institute of Organic Synthesis, Ural Branch; Institute of Chemistry, Far Eastern Branch

Author for correspondence.
Email: pestov@ios.uran.ru
Russian Federation, ul. Sof’ i Kovalevskoi 22, Yekaterinburg, 620137; pr. 100-letiya Vladivostoka, Vladivostok, 690022

O. V. Koryakova

Postovskii Institute of Organic Synthesis, Ural Branch

Email: pestov@ios.uran.ru
Russian Federation, ul. Sof’ i Kovalevskoi 22, Yekaterinburg, 620137

Yu. O. Privar

Institute of Chemistry, Far Eastern Branch

Email: pestov@ios.uran.ru
Russian Federation, pr. 100-letiya Vladivostoka, Vladivostok, 690022

S. Yu. Bratskaya

Institute of Chemistry, Far Eastern Branch

Email: pestov@ios.uran.ru
Russian Federation, pr. 100-letiya Vladivostoka, Vladivostok, 690022

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