Autoclave Processing of Concentrates Containing Stable Form of Palladium Oxide
- Авторы: Belousov O.V.1,2, Belousova N.V.2, Borisov R.V.1, Grizan N.V.2, Ryumin A.I.2
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Учреждения:
- Institute of Chemistry and Chemical Technology, Federal Research Center, Krasnoyarsk Scientific Center, Siberian Branch
- Siberian Federal University
- Выпуск: Том 91, № 4 (2018)
- Страницы: 550-554
- Раздел: Inorganic Synthesis and Industrial Inorganic Chemistry
- URL: https://journals.rcsi.science/1070-4272/article/view/215770
- DOI: https://doi.org/10.1134/S1070427218040031
- ID: 215770
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Аннотация
Stable modification of palladium oxide and a material modeling the palladium-containing platinum–palladium concentrate poorly soluble in acids were synthesized. It was found that silica is dissolved in alkaline solutions of sodium formate, and palladium oxide is quantitatively reduced under autoclave conditions, which improves the parameters of the subsequent hydrochlorination of the concentrate. Raising the temperature results in that the separation of the palladium phase from alkaline solution is improved and enables separation via decantation.
Об авторах
O. Belousov
Institute of Chemistry and Chemical Technology, Federal Research Center, Krasnoyarsk Scientific Center, Siberian Branch; Siberian Federal University
Автор, ответственный за переписку.
Email: ov_bel@icct.ru
Россия, ul. Karla Marksa 42, Krasnoyarsk, 660049; Svobodnyi pr. 79, Krasnoyarsk, 660041
N. Belousova
Siberian Federal University
Email: ov_bel@icct.ru
Россия, Svobodnyi pr. 79, Krasnoyarsk, 660041
R. Borisov
Institute of Chemistry and Chemical Technology, Federal Research Center, Krasnoyarsk Scientific Center, Siberian Branch
Email: ov_bel@icct.ru
Россия, ul. Karla Marksa 42, Krasnoyarsk, 660049
N. Grizan
Siberian Federal University
Email: ov_bel@icct.ru
Россия, Svobodnyi pr. 79, Krasnoyarsk, 660041
A. Ryumin
Siberian Federal University
Email: ov_bel@icct.ru
Россия, Svobodnyi pr. 79, Krasnoyarsk, 660041
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