Hydroconversion of Oxidation Products of Sulfur-Containing Aromatic Compounds

A. V. Vutolkina; A. V. Akopyan; A. P. Glotov; M. S. Kotelev; A. L. Maksimov; E. A. Karakhanov

doi:10.1134/S1070427218060162

Hydroconversion of Oxidation Products of Sulfur-Containing Aromatic Compounds

Autores: Vutolkina A.V.¹, Akopyan A.V.¹, Glotov A.P.², Kotelev M.S.², Maksimov A.L.¹^,3, Karakhanov E.A.¹
Afiliações:
1. Moscow State University
2. Gubkin Russian State University of Oil and Gas (Natural Research University)
3. Topchiev Institute of Petrochemical Synthesis
Edição: Volume 91, Nº 6 (2018)
Páginas: 981-989
Seção: Organic Synthesis and Industrial Organic Chemistry
URL: https://journals.rcsi.science/1070-4272/article/view/215893
DOI: https://doi.org/10.1134/S1070427218060162
ID: 215893

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Somente assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

Hydroconversion of benzo- and dibenzothiophene sulfone on a Ni–Mo sulfide catalyst based on mesoporous aluminosilicate Al-HMS and on unsupported catalysts prepared in situ in the course of decomposition of poorly soluble precursors (molybdenum hexacarbonyl, nickel naphthenate) was studied. Hydrogenation of sulfones was perfpormed at 250, 340, and 380°С and elevated СО pressure in the presence of water ensuring in situ generation of hydrogen via water-gas shift reaction.