Volatile zirconium compounds: Prospects for use in gas-phase isotope separation
- Авторлар: Igumenov I.K.1, Turgambaeva A.E.1, Krisyuk V.V.1
-
Мекемелер:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Шығарылым: Том 89, № 12 (2016)
- Беттер: 1903-1931
- Бөлім: Reviews
- URL: https://journals.rcsi.science/1070-4272/article/view/214510
- DOI: https://doi.org/10.1134/S1070427216120016
- ID: 214510
Дәйексөз келтіру
Аннотация
Data on volatile zirconium(IV) complexes are considered from the viewpoint of search for compounds exhibiting the required thermal parameters for centrifugal separation of stable isotopes. The results of studies concerning thermodynamics of vaporization of volatile zirconium compounds with inorganic and organic ligands are summarized and analyzed. The influence of the electronic structure of the central atom and of the molecular and crystal structure on the volatility of zirconium compounds is discussed. Promising lines of searching for volatile zirconium compounds for the development of low-activation materials based on isotopically altered elements are outlined.
Авторлар туралы
I. Igumenov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Хат алмасуға жауапты Автор.
Email: igumen@niic.nsc.ru
Ресей, Novosibursk
A. Turgambaeva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: igumen@niic.nsc.ru
Ресей, Novosibursk
V. Krisyuk
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: igumen@niic.nsc.ru
Ресей, Novosibursk
Қосымша файлдар
