Email this article Study of Transport Properties and Microstructure of Lithium-Conducting Li0.33La0.56TiO3 Ceramic
- Authors: Kunshina G.B.1, Shcherbina O.B.1, Ivanenko V.I.1
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Affiliations:
- Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Resources, Kola Scientific Center
- Issue: Vol 92, No 10 (2019)
- Pages: 1351-1358
- Section: Inorganic Synthesis and Industrial Inorganic Chemistry
- URL: https://journals.rcsi.science/1070-4272/article/view/216717
- DOI: https://doi.org/10.1134/S1070427219100045
- ID: 216717
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Abstract
Methods of X-ray diffraction analysis, impedance spectroscopy, and scanning electron microscopy were used to examine how thermal treatment modes affect the transport properties and microstructure of a lithium-conducting oxide ceramic of composition Li0.33La0.56TiO3, produced from powders synthesized by the sol-gel method. It was found that the cubic structure of Li0.33La0.56TiO3 can be stabilized as a result of quenching after the high-temperature of sintering at 1150°C. The conditions were determined in which Li0.33La0.56TiO3 ceramic samples can be obtained with bulk ion conductivity of ∼1 × 10−3 S cm−1 at 20°C, which corresponds to the maximum values for the ceramic based on lithium-lanthanum titanate.
About the authors
G. B. Kunshina
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Resources, Kola Scientific Center
Author for correspondence.
Email: kunshina@chemy.kolasc.net.ru
Russian Federation, Apatity, Murmansk oblast, 184209
O. B. Shcherbina
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Resources, Kola Scientific Center
Email: kunshina@chemy.kolasc.net.ru
Russian Federation, Apatity, Murmansk oblast, 184209
V. I. Ivanenko
Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Resources, Kola Scientific Center
Email: kunshina@chemy.kolasc.net.ru
Russian Federation, Apatity, Murmansk oblast, 184209
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