Electrochemical oxidation of dyes on oxide lead anode with the involvement of active oxygen species


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Abstract

Kinetics and selectivity of oxidation of dyes (Methyl Orange and Chrome Dark Blue) on a lead dioxide (Pb/PbO2) anode at various current densities, substrate concentrations, and pH values with the use of various active oxygen species was studied. It was shown that the electrochemical oxidation of dyes on the Pb/PbO2 anode occurs rather effectively under the chosen conditions. The mineralization efficiency in 5 h was 51 to 89.5 and 93 to 100% for, respectively, Methyl Orange and Chrome Dark Blue, depending on the electrolysis conditions.

About the authors

G. V. Kornienko

Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch

Email: kta@icct.ru
Russian Federation, Akademgorodok 50, str. 24, Krasnoyarsk, 660036

T. A. Kenova

Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch

Author for correspondence.
Email: kta@icct.ru
Russian Federation, Akademgorodok 50, str. 24, Krasnoyarsk, 660036

V. L. Kornienko

Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch

Email: kta@icct.ru
Russian Federation, Akademgorodok 50, str. 24, Krasnoyarsk, 660036

O. A. Golubtsova

Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch; Siberian State Aerospace University named after M.F. Reshetnev

Email: kta@icct.ru
Russian Federation, Akademgorodok 50, str. 24, Krasnoyarsk, 660036; ul. Yunosti 18, Krasnoyarsk, 660123

N. G. Maksimov

Institute of Chemistry and Chemical Technology, Krasnoyarsk Scientific Center, Siberian Branch

Email: kta@icct.ru
Russian Federation, Akademgorodok 50, str. 24, Krasnoyarsk, 660036

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